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Issue 7, 2017
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Introducing unactivated acyclic internal aliphatic olefins into a cobalt catalyzed allylic selective dehydrogenative Heck reaction

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Abstract

Unactivated acyclic internal aliphatic olefins are often found to be unreactive in conventional alkenylation reactions. To address this problem, a cobalt catalyzed allylic selective dehydrogenative Heck reaction with internal aliphatic olefins has been developed. The method is highly regio- and stereoselective, the conditions are mild and a wide variety of functional groups can be tolerated. Remarkably, both internal and terminal aliphatic olefins can be employed, thereby significantly expanding the scope of alkenylation chemistry with aliphatic olefins.

Graphical abstract: Introducing unactivated acyclic internal aliphatic olefins into a cobalt catalyzed allylic selective dehydrogenative Heck reaction

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Publication details

The article was received on 16 Mar 2017, accepted on 13 May 2017 and first published on 16 May 2017


Article type: Edge Article
DOI: 10.1039/C7SC01204G
Citation: Chem. Sci., 2017,8, 5181-5185
  • Open access: Creative Commons BY-NC license
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    Introducing unactivated acyclic internal aliphatic olefins into a cobalt catalyzed allylic selective dehydrogenative Heck reaction

    S. Maity, P. Dolui, R. Kancherla and D. Maiti, Chem. Sci., 2017, 8, 5181
    DOI: 10.1039/C7SC01204G

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