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Copper-catalyzed oxidative C(sp3)–H/C(sp2)–H cross-coupling en route to carbocyclic rings

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Abstract

Copper-catalyzed selective coupling of C(sp3)–H bonds with C(sp2)–H bonds has been developed. An aniline module was used as a directing group to generate an aminyl radical, which selectively cleaves the secondary and tertiary C(sp3)–H bonds via a 1,5-HAT process to forge six-membered carbocyclic rings.

Graphical abstract: Copper-catalyzed oxidative C(sp3)–H/C(sp2)–H cross-coupling en route to carbocyclic rings

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Publication details

The article was received on 18 Jan 2017, accepted on 14 Mar 2017 and first published on 15 Mar 2017


Article type: Edge Article
DOI: 10.1039/C7SC00250E
Citation: Chem. Sci., 2017, Advance Article
  • Open access: Creative Commons BY license
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    Copper-catalyzed oxidative C(sp3)–H/C(sp2)–H cross-coupling en route to carbocyclic rings

    R. Wang, Y. Li, R. Jin and X. Wang, Chem. Sci., 2017, Advance Article , DOI: 10.1039/C7SC00250E

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