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Manganese-catalyzed allylation via sequential C–H and C–C/C–Het bond activation

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Abstract

Manganese-catalyzed sequential C–H and C–C/C–Het bond activation to synthesize allylic alcohols, allylated arenes, functionalized cyclopentenes and skipped dienes is reported. This protocol can be readily scaled up and various coupling partners are applied in manganese catalysis for the first time. Moreover, manganese-catalyzed alkenyl C(sp2)–H activation is also shown. Complimentary to the standard solution-based protocols, these reactions also proceed efficiently under neat conditions, which is unprecedented for abundant metal catalyzed C–H activation reactions.

Graphical abstract: Manganese-catalyzed allylation via sequential C–H and C–C/C–Het bond activation

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Publication details

The article was received on 16 Jan 2017, accepted on 24 Feb 2017 and first published on 24 Feb 2017


Article type: Edge Article
DOI: 10.1039/C7SC00230K
Citation: Chem. Sci., 2017, Advance Article
  • Open access: Creative Commons BY license
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    Manganese-catalyzed allylation via sequential C–H and C–C/C–Het bond activation

    Q. Lu, F. J. R. Klauck and F. Glorius, Chem. Sci., 2017, Advance Article , DOI: 10.1039/C7SC00230K

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