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Issue 5, 2017
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Rh-catalyzed regiodivergent hydrosilylation of acyl aminocyclopropanes controlled by monophosphine ligands

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Abstract

A Rh-catalyzed regiodivergent hydrosilylation of acyl aminocyclopropanes has been developed. Acyl aminocyclopropanes were reacted with hydrosilanes in the presence of Rh catalysts to afford ring-opened hydrosilylated adducts through carbon–carbon (C–C) bond cleavage of the cyclopropane ring. The regioselectivity of the addition of silanes (linear or branched) can be switched by changing the monophosphine ligand. This C–C bond cleavage/hydrosilylation methodology is applicable to the synthesis of silanediol precursors.

Graphical abstract: Rh-catalyzed regiodivergent hydrosilylation of acyl aminocyclopropanes controlled by monophosphine ligands

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Publication details

The article was received on 06 Jan 2017, accepted on 14 Mar 2017 and first published on 15 Mar 2017


Article type: Edge Article
DOI: 10.1039/C7SC00071E
Citation: Chem. Sci., 2017,8, 3799-3803
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    Rh-catalyzed regiodivergent hydrosilylation of acyl aminocyclopropanes controlled by monophosphine ligands

    H. Kondo, K. Itami and J. Yamaguchi, Chem. Sci., 2017, 8, 3799
    DOI: 10.1039/C7SC00071E

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