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Issue 4, 2017
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Cobalt-catalysed C–H carbonylative cyclisation of aliphatic amides

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Abstract

A cobalt-catalysed C–H carbonylation of aliphatic carboxamide derivatives is described, employing commercially available Co(II)-salts in the presence of a silver oxidant. This operationally simple process utilises an atmospheric pressure of CO and generates a range of substituted succinimide products bearing diverse functional groups that can be successfully accessed via this methodology.

Graphical abstract: Cobalt-catalysed C–H carbonylative cyclisation of aliphatic amides

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Publication details

The article was received on 20 Dec 2016, accepted on 05 Jan 2017 and first published on 10 Jan 2017


Article type: Edge Article
DOI: 10.1039/C6SC05581H
Citation: Chem. Sci., 2017,8, 2588-2591
  • Open access: Creative Commons BY license
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    Cobalt-catalysed C–H carbonylative cyclisation of aliphatic amides

    P. Williamson, A. Galván and M. J. Gaunt, Chem. Sci., 2017, 8, 2588
    DOI: 10.1039/C6SC05581H

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