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Micromixing enables chemoselective reactions of difunctional electrophiles with functional aryllithiums

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Abstract

Generation of highly unstable functional aryllithiums followed by chemoselective reactions with difunctional electrophiles were successfully achieved using flow microreactor systems equipped with micromixers to give highly functionalized compounds without protecting functional groups. Extremely fast micromixing is responsible for high chemoselectivity.

Graphical abstract: Micromixing enables chemoselective reactions of difunctional electrophiles with functional aryllithiums

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Publication details

The article was received on 07 Sep 2017, accepted on 06 Oct 2017 and first published on 16 Oct 2017


Article type: Paper
DOI: 10.1039/C7RE00142H
Citation: React. Chem. Eng., 2017, Advance Article
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    Micromixing enables chemoselective reactions of difunctional electrophiles with functional aryllithiums

    A. Nagaki, S. Ishiuchi, K. Imai, K. Sasatsuki, Y. Nakahara and J. Yoshida, React. Chem. Eng., 2017, Advance Article , DOI: 10.1039/C7RE00142H

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