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Issue 5, 2017
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Towards a sustainable electrochemical activation for recycling CO2: synthesis of bis-O-alkylcarbamates from aliphatic and benzyl diamines

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Abstract

Carboxylation of aliphatic and benzyl diamines with electrochemically activated CO2 led to the synthesis of bis-O-alkyl carbamates in high yields. Reaction conditions, including the geometry of the electrochemical cell, were discussed and optimized. This resulted in a significant reduction of unwanted material associated with the reaction, overcoming the economic and environmental restrictions to its application on large scale.

Graphical abstract: Towards a sustainable electrochemical activation for recycling CO2: synthesis of bis-O-alkylcarbamates from aliphatic and benzyl diamines

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Publication details

The article was received on 12 Jul 2017, accepted on 29 Aug 2017 and first published on 29 Aug 2017


Article type: Communication
DOI: 10.1039/C7RE00101K
Citation: React. Chem. Eng., 2017,2, 646-649
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    Towards a sustainable electrochemical activation for recycling CO2: synthesis of bis-O-alkylcarbamates from aliphatic and benzyl diamines

    G. Forte, I. Chiarotto, F. Richter, V. Trieu and M. Feroci, React. Chem. Eng., 2017, 2, 646
    DOI: 10.1039/C7RE00101K

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