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Cobalt-Catalyzed Asymmetric Reactions of Heterobicyclic Alkenes with in situ Generated Organozinc Halides

Abstract

A general strategy for the asymmetric allylation and benzylation of heterobicyclic alkenes were described by employing the in situ generated organozinc halides. The methodology features the application of a co-catalytic system comprising chiral cobalt complex and Lewis acid, delivers both the asymmetric ring opening products of oxabenzonorbornadienes and the asymmetric addition products of azabenzonorbornadienes respectively.

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Publication details

The article was received on 28 Nov 2017, accepted on 22 Dec 2017 and first published on 22 Dec 2017


Article type: Research Article
DOI: 10.1039/C7QO01064H
Citation: Org. Chem. Front., 2017, Accepted Manuscript
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    Cobalt-Catalyzed Asymmetric Reactions of Heterobicyclic Alkenes with in situ Generated Organozinc Halides

    Y. Li, J. Chen, Z. He, H. Qin, Y. Zhou, R. Khan and B. Fan, Org. Chem. Front., 2017, Accepted Manuscript , DOI: 10.1039/C7QO01064H

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