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Rhodium-catalyzed intramolecular carbosilylation of alkynes via C(sp3)–Si bond cleavage

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Abstract

A Rh(I)-catalyzed intramolecular cis-carbosilylation of alkynes was achieved. The cleavage of an alkyl–Si bond in a trimethylsilyl group of 8-alkynyl naphthalene derivatives was followed by cis-addition to the alkynyl moiety, affording silatricyclic compounds in good yields.

Graphical abstract: Rhodium-catalyzed intramolecular carbosilylation of alkynes via C(sp3)–Si bond cleavage

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Publication details

The article was received on 11 Oct 2017, accepted on 02 Dec 2017 and first published on 04 Dec 2017


Article type: Research Article
DOI: 10.1039/C7QO00927E
Citation: Org. Chem. Front., 2018, Advance Article
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    Rhodium-catalyzed intramolecular carbosilylation of alkynes via C(sp3)–Si bond cleavage

    Q. Yang, L. Liu, Y. Chi, W. Hao, W. Zhang and Z. Xi, Org. Chem. Front., 2018, Advance Article , DOI: 10.1039/C7QO00927E

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