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Photoredox 1,2-Dicarbofunctionalization of Unactivated Alkenes via Tandem Radical Difluoroalkylation and Alknyl Migration

Abstract

Visible-light-mediated tandem radical difluoroalkylation and alkynylation of unactivated alkenes was described in this communication. It comprises a mild C-C bond activation via intramolecular 1,4-radical alkynyl migration. The general and elegant protocol can serve as one straightforward access to a wide range of synthetically valuable difluoroalkylated linear alkynyl ketones under mild reaction conditions.

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Publication details

The article was received on 07 Sep 2017, accepted on 03 Nov 2017 and first published on 06 Nov 2017


Article type: Research Article
DOI: 10.1039/C7QO00808B
Citation: Org. Chem. Front., 2017, Accepted Manuscript
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    Photoredox 1,2-Dicarbofunctionalization of Unactivated Alkenes via Tandem Radical Difluoroalkylation and Alknyl Migration

    J. Liu, W. Li, J. Xie and C. Zhu, Org. Chem. Front., 2017, Accepted Manuscript , DOI: 10.1039/C7QO00808B

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