Issue 1, 2018

The regioselective synthesis of 2-phosphinoylindoles via Rh(iii)-catalyzed C–H activation

Abstract

The redox-neutral annulation of N-nitrosoanilines with 1-alkynylphosphine oxides under rhodium catalysis was achieved. This step-economical protocol affords 2-phosphinoylindoles in excellent regioselectivity with good functional group tolerance.

Graphical abstract: The regioselective synthesis of 2-phosphinoylindoles via Rh(iii)-catalyzed C–H activation

Supplementary files

Article information

Article type
Research Article
Submitted
22 Aug 2017
Accepted
21 Sep 2017
First published
22 Sep 2017

Org. Chem. Front., 2018,5, 88-91

The regioselective synthesis of 2-phosphinoylindoles via Rh(III)-catalyzed C–H activation

H. Wang, S. Li, B. Wang and B. Li, Org. Chem. Front., 2018, 5, 88 DOI: 10.1039/C7QO00746A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements