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Issue 11, 2017
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Catalytic and catalyst-free diboration of alkynes

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Abstract

The diboration of alkynes has become the most straightforward and powerful method for the synthesis of functionalized 1,2-diborylalkenes, which are widely used as building blocks in organic synthesis. The present review provides a comprehensive summary of the diboration of alkynes, including platinum-, palladium-, cobalt-, copper-, iridium-, gold-, iron-, base- and small organic molecule-catalyzed diboration, direct and metal-free diboration, and base-promoted diboration of alkynes up to early 2017. The reaction conditions, regio- and stereoselectivities, and mechanisms are summarized in detail. Moreover, synthetic applications and perspectives on the diboration of alkynes are also discussed.

Graphical abstract: Catalytic and catalyst-free diboration of alkynes

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Publication details

The article was received on 21 Jul 2017, accepted on 28 Aug 2017 and first published on 05 Sep 2017


Article type: Review Article
DOI: 10.1039/C7QO00614D
Citation: Org. Chem. Front., 2017,4, 2235-2255
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    Catalytic and catalyst-free diboration of alkynes

    F. Zhao, X. Jia, P. Li, J. Zhao, Y. Zhou, J. Wang and H. Liu, Org. Chem. Front., 2017, 4, 2235
    DOI: 10.1039/C7QO00614D

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