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Divergent synthesis of hydropyridine derivatives via nitrogen-containing Lewis base mediated regioselective [4 + 2] cyclizations

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Abstract

A nitrogen-containing Lewis base mediated regioselective [4 + 2] cyclization strategy between allenic esters and α,β-unsaturated ketimines was discovered, affording a series of hydropyridine derivatives in moderate to good yields under mild conditions.

Graphical abstract: Divergent synthesis of hydropyridine derivatives via nitrogen-containing Lewis base mediated regioselective [4 + 2] cyclizations

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Publication details

The article was received on 18 Jul 2017, accepted on 16 Aug 2017 and first published on 16 Aug 2017


Article type: Research Article
DOI: 10.1039/C7QO00596B
Citation: Org. Chem. Front., 2017, Advance Article
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    Divergent synthesis of hydropyridine derivatives via nitrogen-containing Lewis base mediated regioselective [4 + 2] cyclizations

    H. Jin, E. Li and Y. Huang, Org. Chem. Front., 2017, Advance Article , DOI: 10.1039/C7QO00596B

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