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1,2,3-Triazole-assisted C–H amidation by cobalt(III) catalysis

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Abstract

A procedure for the [Cp*CoIII]-catalyzed, 1,2,3-triazole directed C–H amidation of arenes, using dioxazolone as an efficient amidating reagent, has been developed. This reaction provides a step- and atom-economical protocol for C–N bond formation, releasing carbon dioxide as a single byproduct. Yet a variety of functional groups are well tolerated, obtaining the desired products in moderate to excellent yields.

Graphical abstract: 1,2,3-Triazole-assisted C–H amidation by cobalt(iii) catalysis

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Publication details

The article was received on 05 Jul 2017, accepted on 09 Aug 2017 and first published on 10 Aug 2017


Article type: Research Article
DOI: 10.1039/C7QO00556C
Citation: Org. Chem. Front., 2017, Advance Article
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    1,2,3-Triazole-assisted C–H amidation by cobalt(III) catalysis

    X. Yu, Q. Ma, S. Lv, J. Li, C. Zhang, L. Hai, Q. Wang and Y. Wu, Org. Chem. Front., 2017, Advance Article , DOI: 10.1039/C7QO00556C

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