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Issue 11, 2017
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Ir(III)-Catalyzed site-selective amidation of azoxybenzenes and late-stage transformation

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Abstract

An efficient ortho C–H amidation of azoxybenzenes with 1,4,2-dioxazol-5-ones under Ir(III)-catalysis has been developed. This simple amidation reaction provides a new protocol for the diversification of azoxybenzenes, and affords the aminated products in moderate to good yields. Meanwhile, an investigation of the late-stage transformation of products is also presented in this text.

Graphical abstract: Ir(iii)-Catalyzed site-selective amidation of azoxybenzenes and late-stage transformation

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Publication details

The article was received on 01 Jul 2017, accepted on 10 Aug 2017 and first published on 11 Aug 2017


Article type: Research Article
DOI: 10.1039/C7QO00542C
Citation: Org. Chem. Front., 2017,4, 2202-2206
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    Ir(III)-Catalyzed site-selective amidation of azoxybenzenes and late-stage transformation

    W. Zhang, H. Deng and H. Li, Org. Chem. Front., 2017, 4, 2202
    DOI: 10.1039/C7QO00542C

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