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Ir(III)-catalyzed site-selective amidation of azoxybenzenes and late-stage transformations

Abstract

An efficient ortho C–H amidation of azoxybenzenes with 1,4,2-dioxazol-5-ones under Ir(III)-catalysis has been developed. This simple amidation reaction provides a new protocol for the diversification of azoxybenzenes, and affords the aminated products in moderate to good yields. Meanwhile, the illustrative investigation on the late-stage transformation of product is also presented in this text.

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Publication details

The article was received on 01 Jul 2017, accepted on 10 Aug 2017 and first published on 11 Aug 2017


Article type: Research Article
DOI: 10.1039/C7QO00542C
Citation: Org. Chem. Front., 2017, Accepted Manuscript
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    Ir(III)-catalyzed site-selective amidation of azoxybenzenes and late-stage transformations

    W. Zhang, H. Deng and H. Li, Org. Chem. Front., 2017, Accepted Manuscript , DOI: 10.1039/C7QO00542C

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