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Issue 9, 2017
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Identifying a cobalt catalyst for highly selective hydrosilylation of allenes

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Abstract

An efficient method of cobalt-catalyzed allene-hydrosilylation is developed. The reaction enjoys an excellent regio- and stereoselectivity and a broad scope affording Z-allylic silanes. Many synthetically useful functional groups can be tolerated. A Co(I)-species involved mechanism is proposed.

Graphical abstract: Identifying a cobalt catalyst for highly selective hydrosilylation of allenes

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Publication details

The article was received on 21 Jun 2017, accepted on 16 Jul 2017 and first published on 18 Jul 2017


Article type: Research Article
DOI: 10.1039/C7QO00497D
Citation: Org. Chem. Front., 2017,4, 1829-1832
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    Identifying a cobalt catalyst for highly selective hydrosilylation of allenes

    Z. Yang, D. Peng, X. Du, Z. Huang and S. Ma, Org. Chem. Front., 2017, 4, 1829
    DOI: 10.1039/C7QO00497D

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