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Silver-mediated fluorination of alkyl iodides with TMSCF3 as the fluorinating agent

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Abstract

The first example of a silver-mediated fluorination of alkyl iodides with the Ruppert–Prakash reagent (TMSCF3) as a fluorinating agent has been reported. This reaction is compatible with a variety of functional groups and proceeds under mild reaction conditions. Moreover, we demonstrate that the large surface area of CaF2 dramatically increased the reaction yield.

Graphical abstract: Silver-mediated fluorination of alkyl iodides with TMSCF3 as the fluorinating agent

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Publication details

The article was received on 08 Jun 2017, accepted on 26 Jun 2017 and first published on 27 Jun 2017


Article type: Research Article
DOI: 10.1039/C7QO00450H
Citation: Org. Chem. Front., 2017, Advance Article
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    Silver-mediated fluorination of alkyl iodides with TMSCF3 as the fluorinating agent

    L. Wang, X. Jiang and P. Tang, Org. Chem. Front., 2017, Advance Article , DOI: 10.1039/C7QO00450H

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