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Issue 10, 2017
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Fe-Catalyzed insertion of fluoromethylcarbenes generated from sulfonium salts into X–H bonds (X = Si, C, P)

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Abstract

The Fe-catalyzed insertion of fluoromethylcarbenes including trifluoromethylcarbene and difluoromethylcarbene generated in situ from sulfonium salts (Ph2S+CH2CF3OTf and Ph2S+CH2CF2H OTf) into X–H (X = Si, C and P) bonds is described. The insertion of both carbenes into the Si–H bond occurred smoothly, and trifluoromethylcarbene could also insert into C–H and P–H bonds.

Graphical abstract: Fe-Catalyzed insertion of fluoromethylcarbenes generated from sulfonium salts into X–H bonds (X = Si, C, P)

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Publication details

The article was received on 01 Jun 2017, accepted on 19 Jun 2017 and first published on 20 Jun 2017


Article type: Research Article
DOI: 10.1039/C7QO00430C
Citation: Org. Chem. Front., 2017,4, 1917-1920
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    Fe-Catalyzed insertion of fluoromethylcarbenes generated from sulfonium salts into X–H bonds (X = Si, C, P)

    Y. Duan, J. Lin, J. Xiao and Y. Gu, Org. Chem. Front., 2017, 4, 1917
    DOI: 10.1039/C7QO00430C

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