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Iridium-catalyzed intermolecular directed dehydrogenative ortho C–H silylation

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Abstract

An efficient method for iridium-catalyzed direct silylation of C(sp2)–H and C(sp3)–H bonds using HSiMe(OSiMe3)2 as the silylating reagent is described. The reaction is amenable to various directing groups under simple and mild conditions leading to the mono- and regioselective synthesis of versatile organosilane compounds.

Graphical abstract: Iridium-catalyzed intermolecular directed dehydrogenative ortho C–H silylation

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Publication details

The article was received on 28 Apr 2017, accepted on 27 Jun 2017 and first published on 28 Jun 2017


Article type: Research Article
DOI: 10.1039/C7QO00340D
Citation: Org. Chem. Front., 2017, Advance Article
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    Iridium-catalyzed intermolecular directed dehydrogenative ortho C–H silylation

    H. Wang, G. Wang and P. Li, Org. Chem. Front., 2017, Advance Article , DOI: 10.1039/C7QO00340D

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