Issue 10, 2017
From the journal:

Organic Chemistry Frontiers

Iridium-catalyzed intermolecular directed dehydrogenative ortho C–H silylation†

Hong Wang,a   Guanghui Wanga  and  Pengfei Li ORCID logo *a  

* Corresponding authors

a Center for Organic Chemistry, Frontier Institute of Science and Technology, Xi'an Jiaotong University, Xi'an 710054, China
E-mail: lipengfei@mail.xjtu.edu.cn

Abstract

An efficient method for iridium-catalyzed direct silylation of C(sp2)–H and C(sp3)–H bonds using HSiMe(OSiMe3)2 as the silylating reagent is described. The reaction is amenable to various directing groups under simple and mild conditions leading to the mono- and regioselective synthesis of versatile organosilane compounds.

Graphical abstract: Iridium-catalyzed intermolecular directed dehydrogenative ortho C–H silylation

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Article information

DOI
https://doi.org/10.1039/C7QO00340D
Article type
Research Article
Submitted
28 Apr 2017
Accepted
27 Jun 2017
First published
28 Jun 2017

Org. Chem. Front., 2017,4, 1943-1946

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Iridium-catalyzed intermolecular directed dehydrogenative ortho C–H silylation

H. Wang, G. Wang and P. Li, Org. Chem. Front., 2017, 4, 1943 DOI: 10.1039/C7QO00340D

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