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Issue 9, 2017
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Copper-catalyzed oxidative dehydrogenative coupling of carboxylic acids with H-phosphonates: an efficient and practical approach to acyl phosphate esters

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Abstract

A copper-catalyzed oxidative dehydrogenative coupling of carboxylic acids with H-phosphonates is developed. This transformation exhibits a wide substrate scope and good functional group tolerance, providing a straightforward and highly efficient access to acyl phosphate esters. A possible mechanism for the reaction is proposed.

Graphical abstract: Copper-catalyzed oxidative dehydrogenative coupling of carboxylic acids with H-phosphonates: an efficient and practical approach to acyl phosphate esters

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Publication details

The article was received on 18 Apr 2017, accepted on 02 Jun 2017 and first published on 05 Jun 2017


Article type: Research Article
DOI: 10.1039/C7QO00298J
Citation: Org. Chem. Front., 2017,4, 1777-1780
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    Copper-catalyzed oxidative dehydrogenative coupling of carboxylic acids with H-phosphonates: an efficient and practical approach to acyl phosphate esters

    H. Fu, T. Yang, J. Shang, J. Zhou, M. Sun and Y. Li, Org. Chem. Front., 2017, 4, 1777
    DOI: 10.1039/C7QO00298J

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