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Issue 7, 2017
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An expedient E-stereoselective synthesis of multi-substituted functionalized allylic boronates from Morita–Baylis–Hillman alcohols

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Abstract

An expedient and stereoselective synthesis of functionalized trisubstituted allylic boronates via direct borylation of Morita–Baylis–Hillman alcohols is disclosed. The reaction proceeds smoothly at ambient temperature with high atomic and synthetic efficiency. The desired allylic boronates can be applied in the efficient synthesis of homoallyl alcohols and α-exomethylene γ-lactones.

Graphical abstract: An expedient E-stereoselective synthesis of multi-substituted functionalized allylic boronates from Morita–Baylis–Hillman alcohols

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Publication details

The article was received on 31 Mar 2017, accepted on 30 Apr 2017 and first published on 03 May 2017


Article type: Research Article
DOI: 10.1039/C7QO00253J
Citation: Org. Chem. Front., 2017,4, 1220-1223
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    An expedient E-stereoselective synthesis of multi-substituted functionalized allylic boronates from Morita–Baylis–Hillman alcohols

    Q. Xuan, Y. Wei, J. Chen and Q. Song, Org. Chem. Front., 2017, 4, 1220
    DOI: 10.1039/C7QO00253J

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