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Iron-catalyzed boration of allylic esters: an efficient approach to allylic boronates

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Abstract

An efficient approach to allylic boronates via iron-catalyzed boration of allylic esters is described. The reactions of allylic esters and bis(pinacolato)diboron (B2pin2) proceed smoothly catalyzed by FeCl2/PPh3. Thus, a wide range of allylic boronates with broad functional-group compatibility are obtained.

Graphical abstract: Iron-catalyzed boration of allylic esters: an efficient approach to allylic boronates

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Publication details

The article was received on 23 Mar 2017, accepted on 09 May 2017 and first published on 10 May 2017


Article type: Research Article
DOI: 10.1039/C7QO00228A
Citation: Org. Chem. Front., 2017, Advance Article
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    Iron-catalyzed boration of allylic esters: an efficient approach to allylic boronates

    Y. Zhou, H. Wang, Y. Liu, Y. Zhao, C. Zhang and J. Qu, Org. Chem. Front., 2017, Advance Article , DOI: 10.1039/C7QO00228A

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