Jump to main content
Jump to site search


Manganese-mediated/-catalyzed oxidative carboazidation of acrylamides

Author affiliations

Abstract

Manganese-mediated/-catalyzed oxidative carboazidation of acrylamides was developed for the synthesis of various azido oxindoles in 32% to 99% yields. tert-Butyl peroxybenzoate (TBPB) was used as an oxidant for the Mn-catalyzed method. And a Mn(II)/Mn(IV)/Mn(III) catalysis cycle via a stepwise or concerted regeneration of high-valent manganese was proposed for this protocol. This reaction system exhibits great functional group tolerance.

Graphical abstract: Manganese-mediated/-catalyzed oxidative carboazidation of acrylamides

Back to tab navigation
Please wait while Download options loads

Supplementary files

Publication details

The article was received on 18 Mar 2017, accepted on 03 May 2017 and first published on 04 May 2017


Article type: Research Article
DOI: 10.1039/C7QO00217C
Citation: Org. Chem. Front., 2017, Advance Article
  •   Request permissions

    Manganese-mediated/-catalyzed oxidative carboazidation of acrylamides

    D. Zhao, K. Kang, W. Wan, H. Jiang, H. Deng, Y. Chen and J. Hao, Org. Chem. Front., 2017, Advance Article , DOI: 10.1039/C7QO00217C

Search articles by author