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A concise synthetic approach to parvistemin A and (±)-diperezone

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Abstract

A concise synthetic approach to symmetric biquinone skeletons has been developed through a new biomimetic oxidative phenolic coupling of 1,2,4-trihydroxyarenes using K3[Fe(CN)6] or FeCl3 as the oxidant under basic conditions. Merging with the ring expansion process of cyclobutenones, a synthetic strategy to biquinone natural products has been developed. And in the light of this strategy, total syntheses of parvistemin A and (±)-diperezone have been achieved.

Graphical abstract: A concise synthetic approach to parvistemin A and (±)-diperezone

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Publication details

The article was received on 18 Mar 2017, accepted on 23 Apr 2017 and first published on 27 Apr 2017


Article type: Research Article
DOI: 10.1039/C7QO00216E
Citation: Org. Chem. Front., 2017, Advance Article
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    A concise synthetic approach to parvistemin A and (±)-diperezone

    S. Gao and X. Hu, Org. Chem. Front., 2017, Advance Article , DOI: 10.1039/C7QO00216E

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