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Issue 7, 2017
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Transition-metal-free oxidative reaction of hydrazines and potassium metabisulfite for preparation of sulfonohydrazides

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Abstract

A transition-metal-free oxidative coupling reaction for the synthesis of sulfonohydrazides from two types of hydrazines and potassium metabisulfite under air has been developed. This highly selective reaction used one arylhydrazine as an aryl coupling partner and potassium metabisulfite as a sulfur dioxide precursor, which provides a new and green strategy to sulfonohydrazides.

Graphical abstract: Transition-metal-free oxidative reaction of hydrazines and potassium metabisulfite for preparation of sulfonohydrazides

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Publication details

The article was received on 02 Mar 2017, accepted on 22 Mar 2017 and first published on 23 Mar 2017


Article type: Research Article
DOI: 10.1039/C7QO00168A
Citation: Org. Chem. Front., 2017,4, 1313-1317
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    Transition-metal-free oxidative reaction of hydrazines and potassium metabisulfite for preparation of sulfonohydrazides

    Y. Wang, B. Du, W. Sha, H. Mei, J. Han and Y. Pan, Org. Chem. Front., 2017, 4, 1313
    DOI: 10.1039/C7QO00168A

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