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Palladium-catalyzed arene C–H activation/ketone C–H functionalization reaction: route to spirodihydroindenones

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Abstract

A novel palladium and norbornene catalyzed arene C–H activation method to synthesize various spirodihydroindenone derivatives was developed. This method produces spirodihydroindenones employing aryl iodides with 2-(2-bromoethyl)-cyclopentanones via a domino reaction, which simplifies the route of building spiro compounds and expands further applications for functional groups selectivity.

Graphical abstract: Palladium-catalyzed arene C–H activation/ketone C–H functionalization reaction: route to spirodihydroindenones

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Publication details

The article was received on 01 Mar 2017, accepted on 07 Apr 2017 and first published on 12 Apr 2017


Article type: Research Article
DOI: 10.1039/C7QO00164A
Citation: Org. Chem. Front., 2017, Advance Article
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    Palladium-catalyzed arene C–H activation/ketone C–H functionalization reaction: route to spirodihydroindenones

    B. Zhang, H. Hua, L. Gao, C. Liu, Y. Qiu, P. Zhou, Z. Zhou, J. Zhao and Y. Liang, Org. Chem. Front., 2017, Advance Article , DOI: 10.1039/C7QO00164A

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