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Copper-catalyzed highly selective approach to 2-boroallylic silanes from allenylsilanes

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Abstract

A highly chemo- and regioselective copper-catalyzed borylcupration of 1,2-allenylsilanes affords 2-borylallylsilanes by applying the ligand effect. Many synthetically attractive functional groups are well tolerated. As demonstrated, such 2-borylallylsilanes are very useful dimetallic reagents in organic synthesis. A rationale for the regioselectivity switch is provided.

Graphical abstract: Copper-catalyzed highly selective approach to 2-boroallylic silanes from allenylsilanes

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Publication details

The article was received on 18 Feb 2017, accepted on 20 Mar 2017 and first published on 21 Mar 2017


Article type: Research Article
DOI: 10.1039/C7QO00135E
Citation: Org. Chem. Front., 2017, Advance Article
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    Copper-catalyzed highly selective approach to 2-boroallylic silanes from allenylsilanes

    L. Song, W. Yuan and S. Ma, Org. Chem. Front., 2017, Advance Article , DOI: 10.1039/C7QO00135E

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