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Anthroxyl-based biradical: toward the construction of highly stable multi-spin systems

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Abstract

A new two-spin system having two anthroxyl radicals at the 9,10-positions of anthracene was found to be stable even after exposing it to refluxing polar-protic solvents. This stability might be derived from the spin delocalization as well as the steric protection of the spin center by the orthogonally oriented anthracene.

Graphical abstract: Anthroxyl-based biradical: toward the construction of highly stable multi-spin systems

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Publication details

The article was received on 15 Feb 2017, accepted on 14 Mar 2017 and first published on 22 Mar 2017


Article type: Research Article
DOI: 10.1039/C7QO00130D
Citation: Org. Chem. Front., 2017, Advance Article
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    Anthroxyl-based biradical: toward the construction of highly stable multi-spin systems

    Y. Hirao, A. Konishi and T. Kubo, Org. Chem. Front., 2017, Advance Article , DOI: 10.1039/C7QO00130D

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