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A facile approach to ketones via Pd-catalyzed sequential carbonylation of olefins with formic acid

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Abstract

An effective palladium-catalyzed sequential carbonylation of olefins with formic acid is described. Ketones and the corresponding α,β-enones can be obtained with up to 90% yield. The reaction process is operationally simple and requires no toxic CO.

Graphical abstract: A facile approach to ketones via Pd-catalyzed sequential carbonylation of olefins with formic acid

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Publication details

The article was received on 09 Feb 2017, accepted on 22 Feb 2017 and first published on 22 Feb 2017


Article type: Research Article
DOI: 10.1039/C7QO00111H
Citation: Org. Chem. Front., 2017, Advance Article
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    A facile approach to ketones via Pd-catalyzed sequential carbonylation of olefins with formic acid

    W. Chang, J. Dai, J. Li, Y. Shi, W. Ren and Y. Shi, Org. Chem. Front., 2017, Advance Article , DOI: 10.1039/C7QO00111H

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