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Rhodium-catalyzed denitrogenative transannulation of 1,2,3-triazolyl-carbamates: efficient access to 4-aminooxazolidinones

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Abstract

Herein we describe a novel Rh(II)-catalyzed intramolecular transannulation reaction of 1,2,3-triazolyl carbamates to access functionalized 4-aminooxazolidinones under operationally simple conditions with low catalyst loadings. A one-pot tandem Cu(I)-catalyzed synthesis of 1,2,3-triazolyl-carbamates from propargyl carbamates followed by their rearrangement/cyclization with Rh(II)-carboxylates was also presented.

Graphical abstract: Rhodium-catalyzed denitrogenative transannulation of 1,2,3-triazolyl-carbamates: efficient access to 4-aminooxazolidinones

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Publication details

The article was received on 06 Feb 2017, accepted on 13 Apr 2017 and first published on 17 Apr 2017


Article type: Research Article
DOI: 10.1039/C7QO00101K
Citation: Org. Chem. Front., 2017, Advance Article
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    Rhodium-catalyzed denitrogenative transannulation of 1,2,3-triazolyl-carbamates: efficient access to 4-aminooxazolidinones

    K. Pal and C. M. R. Volla, Org. Chem. Front., 2017, Advance Article , DOI: 10.1039/C7QO00101K

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