Jump to main content
Jump to site search
PLANNED MAINTENANCE Close the message box

Scheduled maintenance upgrade on Thursday 4th of May 2017 from 8.00am to 9.00am (BST).

During this time our websites will be offline temporarily. If you have any questions please use the feedback button on this page. We apologise for any inconvenience this might cause and thank you for your patience.



Rhodium-catalyzed denitrogenative transannulation of 1,2,3-triazolyl-carbamates: efficient access to 4-aminooxazolidinones

Author affiliations

Abstract

Herein we describe a novel Rh(II)-catalyzed intramolecular transannulation reaction of 1,2,3-triazolyl carbamates to access functionalized 4-aminooxazolidinones under operationally simple conditions with low catalyst loadings. A one-pot tandem Cu(I)-catalyzed synthesis of 1,2,3-triazolyl-carbamates from propargyl carbamates followed by their rearrangement/cyclization with Rh(II)-carboxylates was also presented.

Graphical abstract: Rhodium-catalyzed denitrogenative transannulation of 1,2,3-triazolyl-carbamates: efficient access to 4-aminooxazolidinones

Back to tab navigation
Please wait while Download options loads

Supplementary files

Publication details

The article was received on 06 Feb 2017, accepted on 13 Apr 2017 and first published on 17 Apr 2017


Article type: Research Article
DOI: 10.1039/C7QO00101K
Citation: Org. Chem. Front., 2017, Advance Article
  •   Request permissions

    Rhodium-catalyzed denitrogenative transannulation of 1,2,3-triazolyl-carbamates: efficient access to 4-aminooxazolidinones

    K. Pal and C. M. R. Volla, Org. Chem. Front., 2017, Advance Article , DOI: 10.1039/C7QO00101K

Search articles by author