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Issue 7, 2017
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Copper-catalyzed direct borylation of alkyl, alkenyl and aryl halides with B(dan)

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Abstract

Substitutional borylation of C(sp3 or sp2)–halogen bonds with an unsymmetrical diboron [(pin)B–B(dan)] was found to proceed smoothly under copper catalysis. A variety of masked alkyl-, alkenyl- and arylboron compounds [R–B(dan)] were straightforwardly accessible with high functional group compatibility in high yield.

Graphical abstract: Copper-catalyzed direct borylation of alkyl, alkenyl and aryl halides with B(dan)

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Publication details

The article was received on 30 Jan 2017, accepted on 10 Apr 2017 and first published on 10 Apr 2017


Article type: Research Article
DOI: 10.1039/C7QO00084G
Citation: Org. Chem. Front., 2017,4, 1215-1219
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    Copper-catalyzed direct borylation of alkyl, alkenyl and aryl halides with B(dan)

    H. Yoshida, Y. Takemoto, S. Kamio, I. Osaka and K. Takaki, Org. Chem. Front., 2017, 4, 1215
    DOI: 10.1039/C7QO00084G

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