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Aroyl chlorides as novel acyl radical precursors via visible-light photoredox catalysis

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Abstract

Abundant and inexpensive aroyl chlorides have been employed for the first time as novel acyl radical precursors in visible-light photocatalysis. This radical cascade reaction building new C–C bonds is an effective way to synthesize valuable heterocyclic compounds. This approach mainly features a concise redox-neutral mechanism, radical cascade reaction, mild conditions and convenient operations.

Graphical abstract: Aroyl chlorides as novel acyl radical precursors via visible-light photoredox catalysis

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Publication details

The article was received on 05 Jan 2017, accepted on 04 Apr 2017 and first published on 06 Apr 2017


Article type: Research Article
DOI: 10.1039/C7QO00012J
Citation: Org. Chem. Front., 2017, Advance Article
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    Aroyl chlorides as novel acyl radical precursors via visible-light photoredox catalysis

    S. Xu, J. Chen, D. Liu, Y. Bao, Y. Liang and P. Xu, Org. Chem. Front., 2017, Advance Article , DOI: 10.1039/C7QO00012J

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