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Issue 4, 2017
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Nickel-catalyzed carbonylation of arylboronic acids with DMF as a CO source

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Abstract

By using N,N-dimethylformamide (DMF) as a CO source, the cheap metal nickel-catalyzed carbonylation of arylboronic acids was demonstrated as an efficient and facile protocol for the synthesis of diaryl ketones. Results indicated that NiBr2·diglyme was the best pre-catalyst among the investigated transitional metal salts, and excellent yields were achieved via C–H and C–N bond cleavage.

Graphical abstract: Nickel-catalyzed carbonylation of arylboronic acids with DMF as a CO source

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Publication details

The article was received on 01 Jan 2017, accepted on 17 Jan 2017 and first published on 19 Jan 2017


Article type: Research Article
DOI: 10.1039/C7QO00001D
Citation: Org. Chem. Front., 2017,4, 569-572
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    Nickel-catalyzed carbonylation of arylboronic acids with DMF as a CO source

    Y. Li, D. Tu, B. Wang, J. Lu, Y. Wang, Z. Liu, Z. Liu and J. Lu, Org. Chem. Front., 2017, 4, 569
    DOI: 10.1039/C7QO00001D

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