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Issue 4, 2017
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Silver-catalyzed radical carbofluorination of unactivated alkenes with acetic acid in aqueous solution

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Abstract

The AgNO3-catalyzed reactions of unactivated alkenes with acetic acid and Selectfluor reagent in aqueous solution afforded the corresponding γ-fluorinated carboxylic acids under mild conditions. Carbofluorination was not only efficient and regioselective, but also enjoyed a wide functional group compatibility.

Graphical abstract: Silver-catalyzed radical carbofluorination of unactivated alkenes with acetic acid in aqueous solution

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Publication details

The article was received on 26 Dec 2016, accepted on 17 Jan 2017 and first published on 18 Jan 2017


Article type: Research Article
DOI: 10.1039/C6QO00854B
Citation: Org. Chem. Front., 2017,4, 565-568
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    Silver-catalyzed radical carbofluorination of unactivated alkenes with acetic acid in aqueous solution

    H. Chen, L. Zhu and C. Li, Org. Chem. Front., 2017, 4, 565
    DOI: 10.1039/C6QO00854B

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