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5-Azadibenzo[a,g]corannulene

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Abstract

5-Azadibenzo[a,g]corannulene, the first azacorannulene with a nitrogen on the rim, has been synthesized in seven steps from 4-bromoisoquinoline. The strained pyridine ring opens thermally to a polycyclic aromatic nitrile and hydrolytically to an amino aldehyde with the same polycyclic aromatic hydrocarbon framework.

Graphical abstract: 5-Azadibenzo[a,g]corannulene

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Publication details

The article was received on 19 Dec 2016, accepted on 09 Jan 2017, published on 19 Jan 2017 and first published online on 19 Jan 2017


Article type: Research Article
DOI: 10.1039/C6QO00831C
Citation: Org. Chem. Front., 2017, Advance Article
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    5-Azadibenzo[a,g]corannulene

    V. M. Tsefrikas, A. K. Greene and L. T. Scott, Org. Chem. Front., 2017, Advance Article , DOI: 10.1039/C6QO00831C

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