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From tetrabenzoheptafulvalene to sp2 carbon nano-rings

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Abstract

Herein we report a new strategy to construct nano-rings of sp2 carbon by taking advantage of the “C” shape of syn-tetrabenzoheptafulvalene. This strategy led to the successful synthesis of an sp2 carbon nano-ring containing a tetrabenzoheptafulvalene moiety fused with tetraphenylene. However, attempts to synthesize a more strained nano-ring of sp2 carbon using the same strategy only yielded an oxygen-bridged nano-ring with the step of aromatization being unsuccessful. Both the nano-rings were unambiguously characterized by X-ray crystallography.

Graphical abstract: From tetrabenzoheptafulvalene to sp2 carbon nano-rings

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Publication details

The article was received on 19 Dec 2016, accepted on 11 Jan 2017, published on 13 Jan 2017 and first published online on 13 Jan 2017


Article type: Research Article
DOI: 10.1039/C6QO00828C
Citation: Org. Chem. Front., 2017, Advance Article
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    From tetrabenzoheptafulvalene to sp2 carbon nano-rings

    K. Y. Cheung, S. Yang and Q. Miao, Org. Chem. Front., 2017, Advance Article , DOI: 10.1039/C6QO00828C

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