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Issue 4, 2017
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Silver-catalyzed geminal aminofluorination of diazoketones with anilines and N-fluorobenzenesulphonimide

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Abstract

A silver-catalyzed three-component reaction of diazoketones, anilines and NFSI is developed. The reaction provides a new method for gem-aminofluorination of acceptor diazo compounds with aniline as the nitrogen source and NFSI as the fluorine source.

Graphical abstract: Silver-catalyzed geminal aminofluorination of diazoketones with anilines and N-fluorobenzenesulphonimide

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Publication details

The article was received on 14 Dec 2016, accepted on 11 Jan 2017 and first published on 12 Jan 2017


Article type: Research Article
DOI: 10.1039/C6QO00813E
Citation: Org. Chem. Front., 2017,4, 529-533
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    Silver-catalyzed geminal aminofluorination of diazoketones with anilines and N-fluorobenzenesulphonimide

    J. Huang, L. Li, H. Chen, T. Xiao, Y. He and L. Zhou, Org. Chem. Front., 2017, 4, 529
    DOI: 10.1039/C6QO00813E

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