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Issue 4, 2017
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Silver-catalyzed phosphonylation of unprotected propargylic alcohols for the synthesis of allenylphosphoryl compounds

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Abstract

A facile and efficient method of silver-catalyzed phosphonylation of unprotected propargylic alcohols with P(O)H compounds has been established, in which a wide variety of allenylphosphine oxides were obtained in moderate to excellent yields. This transformation could be conducted under mild reaction conditions without a ligand, base, and additive.

Graphical abstract: Silver-catalyzed phosphonylation of unprotected propargylic alcohols for the synthesis of allenylphosphoryl compounds

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The article was received on 30 Nov 2016, accepted on 20 Jan 2017 and first published on 24 Jan 2017


Article type: Research Article
DOI: 10.1039/C6QO00767H
Citation: Org. Chem. Front., 2017,4, 608-611
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    Silver-catalyzed phosphonylation of unprotected propargylic alcohols for the synthesis of allenylphosphoryl compounds

    L. Mao, Y. Li and S. Yang, Org. Chem. Front., 2017, 4, 608
    DOI: 10.1039/C6QO00767H

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