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Issue 4, 2017
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A copper-catalyzed arylation/nucleophilic addition/fragmentation/C–S bond formation cascade: synthesis of bis(arylthio)imines

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Abstract

A new tandem arylation/nucleophilic addition/fragmentation/C–S bond formation reaction involving diaryliodonium salts as electrophiles was developed with Cu(OTf)2 as the catalyst. A series of unexpected bis(arylthio)imine derivatives were generated in good yields. The reaction proceeds under mild conditions, and the bis(arylthio)imines are readily transformed to other useful products.

Graphical abstract: A copper-catalyzed arylation/nucleophilic addition/fragmentation/C–S bond formation cascade: synthesis of bis(arylthio)imines

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Publication details

The article was received on 21 Nov 2016, accepted on 31 Dec 2016 and first published on 03 Jan 2017


Article type: Research Article
DOI: 10.1039/C6QO00739B
Citation: Org. Chem. Front., 2017,4, 510-513
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    A copper-catalyzed arylation/nucleophilic addition/fragmentation/C–S bond formation cascade: synthesis of bis(arylthio)imines

    W. Guo, Y. Wang, Q. Dou, L. Wen and M. Li, Org. Chem. Front., 2017, 4, 510
    DOI: 10.1039/C6QO00739B

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