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Issue 6, 2017
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Towards hydroxamic acid linked zirconium metal–organic frameworks

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Abstract

Solvent-assisted linker exchange (SALE) is performed on the Zr-based metal–organic framework (MOF), UiO-66, to exchange benzene-1,4-dicarboxylate with benzene-1,4-dihydroxamate linkers. Characterization of the material before and after SALE is performed using powder X-ray diffraction (PXRD), scanning electron microscopy (SEM), nitrogen adsorption, diffuse reflectance infrared Fourier transform spectroscopy (DRIFTS) and thermogravimetric analysis (TGA). The stability of the parent and daughter material is evaluated at pH 1 and 12 and the structural integrity evaluated by PXRD, mass balance and porosity measurements.

Graphical abstract: Towards hydroxamic acid linked zirconium metal–organic frameworks

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Publication details

The article was received on 15 Dec 2016, accepted on 23 Jan 2017 and first published on 30 Jan 2017


Article type: Research Article
DOI: 10.1039/C6QM00364H
Citation: Mater. Chem. Front., 2017,1, 1194-1199
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    Towards hydroxamic acid linked zirconium metal–organic frameworks

    C. F. Pereira, A. J. Howarth, N. A. Vermeulen, F. A. Almeida Paz, J. P. C. Tomé, J. T. Hupp and O. K. Farha, Mater. Chem. Front., 2017, 1, 1194
    DOI: 10.1039/C6QM00364H

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