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Issue 1, 2017
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Stimuli responsive furan and thiophene substituted difluoroboron β-diketonate materials

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Abstract

Difluoroboron β-diketonate (BF2bdk) compounds exhibit solid-state switchable luminescence under excitation by UV light. This property is usually manifested as a blue-shift in emission when dye films are thermally annealed followed by a red-shift in response to mechanical shear (i.e. mechanochromic luminescence). Here we report thiophene and furan heterocycle-substituted dyes bearing short methoxy and long dodecyloxy chain substituents. Optical properties of the dyes were investigated in solution, pristine powders, and films on paper and glass. The structural and thermal properties of the dyes were also investigated by powder X-ray diffraction (XRD) and differential scanning calorimetry (DSC), respectively. The methoxy-substituted dyes exhibited neither thermal nor mechano-responsive behavior, however, addition of a longer C12 alkoxyl chain substituent resulted in stimuli-responsive behavior. The furan and thiophene dodecyloxy-substituted dyes both exhibit high-contrast reversible luminescence switching between crystalline, blue-shifted and amorphous red-shifted emissive states. For the furan dye, gentle heating produced a green emissive form while melting followed by rapid cooling produced an orange emissive form. The thiophene dye, on the other hand, exhibited blue-shifted emission when annealed below its melting temperature and red-shifted emission when smeared (mechanochromic luminescence). These transformations for both dyes were found to be completely reversible, making them potential candidates for applications requiring reusable, functional materials.

Graphical abstract: Stimuli responsive furan and thiophene substituted difluoroboron β-diketonate materials

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Publication details

The article was received on 13 Apr 2016, accepted on 11 May 2016 and first published on 29 Jul 2016


Article type: Research Article
DOI: 10.1039/C6QM00008H
Citation: Mater. Chem. Front., 2017,1, 158-166
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    Stimuli responsive furan and thiophene substituted difluoroboron β-diketonate materials

    W. A. Morris, T. Butler, M. Kolpaczynska and C. L. Fraser, Mater. Chem. Front., 2017, 1, 158
    DOI: 10.1039/C6QM00008H

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