Issue 2, 2018

The influence of an external magnetic field and magnetic-site dilution on the magnetization dynamics of a coordination network based on ferromagnetic coupled dinuclear dysprosium(iii) units

Abstract

We report the synthesis and magnetic properties of a μ2-OH bridged dinuclear Dy(III) single-molecule magnet (SMM), [Dy2(apca)42-OH)2(H2O)2]n (Dy, Hapca = 3-aminopyrazine-2-carboxylic acid), which was assembled in a two-dimensional (2D) network. Magnetic studies reveal that Dy exhibits ferromagnetic interactions, multi-process slow relaxation of magnetization and hysteresis loops. The influence of an external magnetic field and magnetic-site dilution on the magnetic properties was also studied.

Graphical abstract: The influence of an external magnetic field and magnetic-site dilution on the magnetization dynamics of a coordination network based on ferromagnetic coupled dinuclear dysprosium(iii) units

Supplementary files

Article information

Article type
Research Article
Submitted
25 Oct 2017
Accepted
06 Dec 2017
First published
06 Dec 2017

Inorg. Chem. Front., 2018,5, 432-437

The influence of an external magnetic field and magnetic-site dilution on the magnetization dynamics of a coordination network based on ferromagnetic coupled dinuclear dysprosium(III) units

X. Zhang, N. Xu, W. Shi, B. Wang and P. Cheng, Inorg. Chem. Front., 2018, 5, 432 DOI: 10.1039/C7QI00663B

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