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Marriage of Phthalocaynine Chemistry with Lanthanides: A Single-Ion Magnet with the Blocking Temperature Up to 25 K

Abstract

One of the most challengeable issues to make single-molecule magnets (SMMs) practicable is how to enhance the working temperature to exhibit the magnetic bistability property. Jiang and co-workers report the new bis(tetrapyrrole) lanthanide double-decker molecule that exhibited the blocking temperature up to 25 K by imcorporating 16 dialkylamino substituents to phthalocaynine periphery. This is a landmark for the marriage of rich phthalocyanine chemistry to lanthanides, which offers an “golden” opportunity to address the critical issue of SMM.

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Publication details

The article was received on 21 Aug 2017, accepted on 10 Sep 2017 and first published on 13 Sep 2017


Article type: Highlight
DOI: 10.1039/C7QI00502D
Citation: Inorg. Chem. Front., 2017, Accepted Manuscript
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    Marriage of Phthalocaynine Chemistry with Lanthanides: A Single-Ion Magnet with the Blocking Temperature Up to 25 K

    J. Zhang, Inorg. Chem. Front., 2017, Accepted Manuscript , DOI: 10.1039/C7QI00502D

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