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Ferroelectricity in bis(ethylammonium) pentachlorobismuthate(III): synthesis, structure, polar and spectroscopic properties

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Abstract

A brief description of the thermal, structural and dielectric properties of bis(ethylammonium) pentachlorobismuthate(III) ferroelectric with Ps that equals to 1.4 μC cm−2 at 180 K is presented. This paper focuses in particular on the molecular mechanism of a phase transition that is related mainly to the deformation of the anionic sublattice confirmed by temperature-variable powdered UV-Vis spectroscopy.

Graphical abstract: Ferroelectricity in bis(ethylammonium) pentachlorobismuthate(iii): synthesis, structure, polar and spectroscopic properties

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The article was received on 09 May 2017, accepted on 01 Jun 2017 and first published on 02 Jun 2017


Article type: Research Article
DOI: 10.1039/C7QI00254H
Citation: Inorg. Chem. Front., 2017, Advance Article
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    Ferroelectricity in bis(ethylammonium) pentachlorobismuthate(III): synthesis, structure, polar and spectroscopic properties

    A. Piecha-Bisiorek, A. Gągor, R. Jakubas, A. Ciżman, R. Janicki and W. Medycki, Inorg. Chem. Front., 2017, Advance Article , DOI: 10.1039/C7QI00254H

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