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Issue 6, 2017
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Tunable design of yolk–shell ZnFe2O4@RGO@TiO2 microspheres for enhanced high-frequency microwave absorption

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Abstract

A series of yolk–shell ZnFe2O4@reduced graphite oxide@TiO2 (ZFO@RGO@TiO2) microspheres with different void sizes and TiO2 shell thicknesses has been successfully synthesized by combining a layer-by-layer coating process and chemical etching route. Compared to pure ZFO and hierarchical ZFO@SiO2@RGO@TiO2, the as-synthesized yolk–shell microspheres exhibited significantly enhanced microwave absorption properties in terms of effective bandwidth and reflection loss. Among these, the minimum reflection loss of the as-synthesized yolk–shell microspheres with a thickness of 2.6 mm could reach up to −44.3 dB at 15.92 GHz, and their effective absorption bandwidth at less than −10 dB was 4.1 GHz. In addition, as the shell thickness of the yolk–shell microspheres decreased, the frequency corresponding to the minimum reflection loss shifted to the high-frequency range. Hence, these obtained yolk–shell microspheres are potential new candidates for high-frequency shielding and lightweight microwave absorbing materials.

Graphical abstract: Tunable design of yolk–shell ZnFe2O4@RGO@TiO2 microspheres for enhanced high-frequency microwave absorption

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Publication details

The article was received on 01 Mar 2017, accepted on 20 Mar 2017 and first published on 21 Mar 2017


Article type: Research Article
DOI: 10.1039/C7QI00120G
Citation: Inorg. Chem. Front., 2017,4, 935-945
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    Tunable design of yolk–shell ZnFe2O4@RGO@TiO2 microspheres for enhanced high-frequency microwave absorption

    J. Feng, Y. Wang, Y. Hou and L. Li, Inorg. Chem. Front., 2017, 4, 935
    DOI: 10.1039/C7QI00120G

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