Jump to main content
Jump to site search

Issue 4, 2017
Previous Article Next Article

A mesoporous (3,36)-connected txt-type metal–organic framework constructed by using a naphthyl-embedded ligand exhibiting high CO2 storage and selectivity

Author affiliations

Abstract

A highly mesoporous (3,36)-connected txt-type metal–organic framework, termed HHU-1, with a naphthalene-embedded ligand was successfully synthesized. HHU-1 exhibits a BET surface area of 2290 m2 g−1 and a high pore volume of 1.33 cm3 g−1. Due to the conjugation effect induced by the naphthyl of ligands, acylamide groups stretching into pores contribute to a comparably higher CO2 adsorption enthalpy (27.7 kJ mol−1), which endows HHU-1 with a high CO2 storage capacity (1071 mg g−1 at 40 bar) as well as high selectivity (CO2 : N2 = 140).

Graphical abstract: A mesoporous (3,36)-connected txt-type metal–organic framework constructed by using a naphthyl-embedded ligand exhibiting high CO2 storage and selectivity

Back to tab navigation

Supplementary files

Publication details

The article was received on 31 Dec 2016, accepted on 24 Feb 2017 and first published on 24 Feb 2017


Article type: Research Article
DOI: 10.1039/C6QI00616G
Citation: Inorg. Chem. Front., 2017,4, 736-740
  •   Request permissions

    A mesoporous (3,36)-connected txt-type metal–organic framework constructed by using a naphthyl-embedded ligand exhibiting high CO2 storage and selectivity

    Z. Lu, J. Zhang, H. He, L. Du and C. Hang, Inorg. Chem. Front., 2017, 4, 736
    DOI: 10.1039/C6QI00616G

Search articles by author

Spotlight

Advertisements