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Enhanced magnetic anisotropy in a tellurium-coordinated cobalt single-ion magnet

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Abstract

A series of tetrahedral Co(II) complexes with chalcogen donors were prepared, which exhibited strong magnetic uniaxial anisotropies and slow relaxations as SIMs. By substituting donors from S to Te, we realized the fine-tuning of the ligand field while keeping the coordination geometry virtually unchanged, yielding the first tellurium-coordinated SIM.

Graphical abstract: Enhanced magnetic anisotropy in a tellurium-coordinated cobalt single-ion magnet

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Publication details

The article was received on 30 Nov 2016, accepted on 27 Jan 2017, published on 08 Feb 2017 and first published online on 08 Feb 2017


Article type: Research Article
DOI: 10.1039/C6QI00543H
Citation: Inorg. Chem. Front., 2017, Advance Article
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    Enhanced magnetic anisotropy in a tellurium-coordinated cobalt single-ion magnet

    X. Yao, M. Yang, J. Xiong, J. Liu, C. Gao, Y. Meng, S. Jiang, B. Wang and S. Gao, Inorg. Chem. Front., 2017, Advance Article , DOI: 10.1039/C6QI00543H

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