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Issue 40, 2017
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Free radical and RAFT polymerization of vinyl esters in metal–organic-frameworks

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Abstract

Free radical and RAFT polymerization of vinyl esters with different molecular dimensions are conducted in the nanochannels of metal–organic-frameworks (MOFs). The combination of MOFs with the RAFT technique enables the synthesis of highly isotactic poly(vinyl ester)s with a controlled molecular weight and narrow molecular weight distribution, and stereocontrolled isotactic-block-atactic vinyl ester block copolymers.

Graphical abstract: Free radical and RAFT polymerization of vinyl esters in metal–organic-frameworks

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Publication details

The article was received on 18 Sep 2017, accepted on 27 Sep 2017 and first published on 29 Sep 2017


Article type: Communication
DOI: 10.1039/C7PY01607G
Citation: Polym. Chem., 2017,8, 6204-6208
  • Open access: Creative Commons BY license
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    Free radical and RAFT polymerization of vinyl esters in metal–organic-frameworks

    J. Hwang, H. Lee, M. Antonietti and B. V. K. J. Schmidt, Polym. Chem., 2017, 8, 6204
    DOI: 10.1039/C7PY01607G

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