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Sequence-controlled molecular layers on surfaces by thiol–ene chemistry: synthesis and multitechnique characterization

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Abstract

Silicon surfaces were functionalized by thiol–ene chemistry using sequential reactions of different α,ω-dienes and α,ω-dithiols bearing marker moieties. A system of six individual layers was achieved and exhaustively characterized by combining independent techniques such as X-ray Photoelectron Spectroscopy, Time-of-Flight Secondary Ion Mass Spectrometry and Atomic Force Microscopy using a molecular ruler system.

Graphical abstract: Sequence-controlled molecular layers on surfaces by thiol–ene chemistry: synthesis and multitechnique characterization

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Publication details

The article was received on 05 Sep 2017, accepted on 11 Sep 2017 and first published on 11 Sep 2017


Article type: Communication
DOI: 10.1039/C7PY01515A
Citation: Polym. Chem., 2017, Advance Article
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    Sequence-controlled molecular layers on surfaces by thiol–ene chemistry: synthesis and multitechnique characterization

    A. Llevot, S. O. Steinmüller, B. Bitterer, B. Ridder, J. Berson, S. Walheim, T. Schimmel, S. Bräse, F. Scheiba and M. A. R. Meier, Polym. Chem., 2017, Advance Article , DOI: 10.1039/C7PY01515A

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